"Your Deepest Partner"
EN TR

Ürünler

Karboksi Metil Selüloz – Yüksek Viskosite

SAFETY DATA SHEET

(According to Regulation (EU) No. 1907/2006 Annex II, amended by Regulation (EU) No. 453/2010.)

1.  IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1 Trade Name                         Sodium Carboxymethylcellulose

1.2 Relevant Uses                     Textile, drilling, adhesives, detergents, paint and other technical applications.

1.3 Producer                              DDC KİMYA SAN.TİC.LTD.ŞTİ.


2.  HAZARDS IDENTIFICATION

2.1 Classification                      Not classified as hazardous according to Regulation (EC) No 1272/2008 and
Directive 1999/45/EC.

2.2 Labelling                              Not applicable to labelling according to Regulation (EC) No 1272/2008 and
Directive 1999/45/EC.

2.3 Other Hazards                     Does not meet the criteria for PBT or vPvB according to Annex XIII of Regulation
(EU) No. 1907/2006.

3.  COMPOSITION/INFORMATION ON INGREDIENTS
This product is to be considered as a preparation according to EU-legislation.

Substance name                       EU #                 CAS #               Concentration    Symbols         Risk phrases

Sodium carboxymethyl cellulose                                   9004-32-4            50-80 %                      - Sodium chloride                               231-598-3            7647-14-5            12-30%                       - Hydroxy acetic acid, sodium salt      220-624-9            2836-32-0            8-20%                         - Dust                                                                                                %                             -

4.  FIRST AID MEASURES
General                         Contact physician if symptoms appears.
Inhalation                     Fresh air and rest. Seek medical advice if symptoms appears.
Skin                               Wash the skin immediately with soap and water.
Eyes                              Important! Immediately rinse with water for at least 15 minutes. Hold eyelids apart. Seek medical advice if symptoms appears.
Ingestion                      Only when conscious, rinse mouth, give plenty of water to drink (approx. 500 ml). Contact physician if larger quantity has been swallowed (show this Safety Data Sheet).

5.  FIRE-FIGHTING MEASURES
Extinguishing media                             Water spray, fog or mist, foam, powder, carbon dioxide.
Special fire fighting procedures          Wear self contained breathing apparatus.
Unusual fire hazards                             High concentrations of dust may form explosive mixture with air.
Hazardous combustion products        Carbon monoxide, carbon dioxide.

6.  ACCIDENTAL RELEASE MEASURES
Personal precautions                            For personal protection see Section 8.
Environmental precautions                  Prevent discharge of larger quantities to drain or water courses.
Methods for cleaning up                       Place in container for disposal according to local regulations. (section 13).
Slippery surface if spilled.

7.  HANDLING AND STORAGE
Handling                                    Avoid handling which leads to dust formation. No sparking tools should be used.
Storage                                      Keep in original container. Store in a dry place.

8.  EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure limits  
Ingredient name TWA STEL References
>Dust Time Weighted Average
4 mg/m3
Short Term Exposure limit >OELs

Comments                                 OELs = EH40/2005 Occupational Exposure Limits 2005. Engineering controls                Mechanical ventilation or local exhaust ventilation may be required. Personal protection
Respiratory                    If ventilation is insufficient, suitable respiratory protection must be provided. Wear mask supplied with: Dust filter P2 (for fine dust).

Hand                              Chemical resistant gloves required for prolonged or repeated contact.
Eyes                               Wear approved safety goggles.

9.  PHYSICAL AND CHEMICAL PROPERTIES

Appearance Powder.    
>Colour >Off white.    
>Odour >Odourless.    
>Flash point (ºC)   Not applicable.    
>Autoignition temperature (ºC)

Density (kg/m3)
>> 280 1500 Temperature (°C) >  25
Bulk density (kg/m3) 300 - 900 kg/m3    
>Viscosity (mPas) >5 - 15000 mPas >Temperature (°C) >25
>pH value diluted solution >7 – 11 >Concentration (%) >1
>Solubility in water >Soluble, gel formation.    
>Other physical data >Not applicable    

(These data are typical for the product and not a specification)

10. STABILITY AND REACTIVITY
Stability                                                Stable under recommended storage and handling conditions (section 7).
Conditions to avoid                             Conditions to be avoided: For storing and keeping, dry and moisture free
environment should be chosen. The packaging should be stored as closed due to the moisture sensitivity of the product. Hazardous decomposition products   No typical hazardous decomposition products known.

11. TOXICOLOGICAL INFORMATION
Toxicological data
Health effects
Respiratory                Inhalation of large quantity of dust may cause irritation of nose, throat and airway.
Skin                             Slightly irritating.
Eyes                            Slightly irritating.
Ingestion                   Very low acute toxicity.
Component                               Sodium carboxymethyl cellulose Toxicological data       LD50. oral rat 15000-27000 mg/kg * Sensitization                Not sensitizing. *
Genotoxicity                Ames' test: Not mutagenic. *
Carcinogenicity           Not carcinogenic. *
Reproduction toxicity Not teratogenic. Not embryotoxic. *
Toxicological information       * Literature data.

12. ECOLOGICAL INFORMATION
Ecotoxicological data
Ecotoxicology              The product does not contain any substance(s) considered as harmful or toxic to aquatic organisms.
Degradation                 Inherently biodegradable
Component                  Sodium carboxymethyl cellulose
Ecotoxicological
Data                               LC50 96 hours fish > 21000 ppm 1
LC50 96 hours fish > 56000 ppm 2
Degradation                 20-70% DOC, Modified SCAS Test (OECD 302A). Inherently biodegradable.
Other information                  1 Fresh water trout, 2 Salt water stickle back.

13. DISPOSAL CONSIDERATIONS
Contaminated packaging         Empty remaining contents.
Empty containers should be taken to an approved waste handling site for recycling or disposal.

14. TRANSPORT INFORMATION

ADR                                            Not dangerous goods IATA                                        Not dangerous goods IMDG_EU                                    Not dangerous goods RID                                                Not dangerous goods
Not classified as dangerous in the meaning of transport regulations.

15. REGULATORY INFORMATION

Labelling according to Regulation (EC) No 1272/2008 and Directive 1999/45/EC.

Further information                  The product does not need to be labelled in accordance with EC directives or respective national laws.
Other regulations

Major Accident Hazard             96/82/EC          Update: 2003
Legislation                                Directive 96/82/EC does not apply

Water contaminating class      WGK 1 slightly water endangering
(Germany)

Notification status

REACH                                       y (positive listing)
On the inventory, or in compliance with the inventory

CH INV                                       n (Negative listing)
The mixture contains a polymer. The monomers for this polymer have been notified.

TSCA                                          y (positive listing) On TSCA Inventory

DSL                                            y (positive listing)
All components of this product are on the Canadian DSL list.

AICS                                           y (positive listing)
On the inventory, or in compliance with the inventory

NZIoC                                         y (positive listing)
On the inventory, or in compliance with the inventory

ENCS                                         y (positive listing)
On the inventory, or in compliance with the inventory

ISHL                                           n (Negative listing)
Not in compliance with the inventory

KECI                                           y (positive listing)
On the inventory, or in compliance with the inventory

PICCS                                        y (positive listing)
On the inventory, or in compliance with the inventory

IECSC                                        y (positive listing)
On the inventory, or in compliance with the inventory

16. OTHER INFORMATION

PBT                               Persistent, bioaccumulative and toxic according to 1907/2006/EC, Annex XIII. vPvB                             Very persistent and very bioaccumulative according to 1907/2006/EC,Annex XIII. OEL                               Occupational exposure limit.
Note: The above information is only given for substances that does not meet the classification criteria.

Notification status explanation

REACH                          1907/2006 (EU)

CH INV                          Switzerland. New notified substances and declared preparations

TSCA                             TSCA Inventory

DSL                               Domestic Substances List (DSL)

AICS                              Australia Inventory of Chemical Substances (AICS)

NZIoC                            New Zealand. Inventory of Chemical Substances

ENCS                            Japan. ENCS - Existing and New Chemical Substances Inventory

ISHL                              Japan. ISHL - Inventory of Chemical Substances (METI)

KECI                              Korea. Korean Exisiting Chemicals Inventory (KECI)

PICCS                           Inventory of Chemicals and Chemical Substances (PICCS)

IECSC                           China. Inventory of Existing Chemical Substances in China (IECSC)

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

Date of compilation     2006-09-01

Date of last issue         2015-02-22