TRIETHYLENE GLYCOL MC
1.CHEMICAL PRODUCT AND COMPANY
IDENTIFICATION
Product information
Trade Name: Triethylene glycol
CAS No: 112-27-6
Other Name: Triglycol
Supplier/Manufacturer DDC KİMYA SAN. TİC.LTD.ŞTİ.
2.HAZARD IDENTIFICATION
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Specific target organ toxicity - single exposure (Category 3)
Classification according to EU Directives 67/548/EEC or 1999/45/EC
Irritating to respiratory system.
2.2 Label elements
Labelling according Regulation (EC) No 1272/2008 [CLP]
Pictogram
Signal word Warning
Hazard statement(s)
H335 May cause respiratory irritation.
Precautionary statement(s)
P261 Avoid breathing vapours.
According to European Directive 67/548/EEC as amended.
Supplemental Hazard none
Statements
According to European Directive 67/548/EEC as amended.
Hazard symbol(s)
R-phrase(s)
R37 Irritating to respiratory system.
S-phrase(s) none
3.COMPOSITION / INFORMATION ON INGREDIENTS
3.1 Substances
Other Name : Triglycol
Formula : C6H14O4
Molecular Weight : 150.17 g/mol
CAS-No : 112-27-6
EC-No : 203-953-2
Product Name CAS-No Content
Triethylene Glycol 112-27-6 ≥ 99.5
4.FIRST AID MEASURES
4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
prolonged or repeated exposure can cause:, Nausea, Headache, Vomiting, To the best of our knowledge,
the chemical, physical, and toxicological properties have not been thoroughly investigated.
5.FIRE FIGHTING MEASURES
5.1 Extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Carbon oxides
5.3 Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
6.ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation.
Evacuate personnel to safe areas.
6.2 Environmental precautions
Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up
Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed
containers for disposal.
6.4 Reference to other sections
For disposal see section 13.
7.HANDLING AND STORAGE
7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Hygroscopic.
8.EXPOSURE CONTROL/PERSONAL PROTECTION
8.1 Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested
and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
Body Protection
impervious clothing, The type of protective equipment must be selected according to the
concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator
with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup
to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
respirator. Use respirators and components tested and approved under appropriate government
standards such as NIOSH (US) or CEN (EU).
9.PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
Appearance Form: clear, viscous liquid
Colour: colourless
Assay ≥ 99.5
Melting point/freezing point Melting point/range: -7 °C - lit.
Initial boiling point and boiling range 125 - 127 °C at 0.1 hPa - lit.
Flash point 166 °C - closed cup
Vapour pressure < 1 hPa at 20 °C
Vapour density 5.18 - (Air = 1.0)
Relative density 1.124 g/ml at 25 °C
Water solubility completely soluble, soluble.
9.2 Other safety information
Surface tension 28.8 mN/m at 10.0 °C
10.STABILITY AND REACTIVITY
10.1 Incompatible materials
Strong oxidizing agents, Strong acids
10.2 Hazardous decomposition products
Other decomposition products - no data available
11.TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - rat - 17,000 mg/kg
Inhalation: Respiratory disorder
LD50 Dermal - rabbit - > 22,500 mg/kg
Skin corrosion/irritation
Skin - Human - Mild skin irritation - Patch Test 24 Hrs.
Skin - rabbit - Mild skin irritation - 24 h
Serious eye damage/eye irritation
Eyes - rabbit - Mild eye irritation
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
Reproductive toxicity - mouse - Oral
Effects on Newborn: Growth statistics (e.g., reduced weight gain).
Reproductive toxicity - mouse - Oral
Effects on Newborn: Physical.
Developmental Toxicity - rat - Oral
Effects on Embryo or Fetus: Fetotoxicity (except death, e.g., stunted fetus). Specific Developmental
Abnormalities: Musculoskeletal system.
Specific target organ toxicity - single exposure
Inhalation - May cause respiratory irritation.
Potential health effects
Inhalation May be harmful if inhaled. Causes respiratory tract irritation.
Ingestion May be harmful if swallowed.
Skin May be harmful if absorbed through skin. May cause skin irritation.
Eyes Causes eye irritation.
Signs and Symptoms of Exposure
prolonged or repeated exposure can cause:, Nausea, Headache, Vomiting, To the best of our knowledge,
the chemical, physical, and toxicological properties have not been thoroughly investigated.
12.ECOLOGICAL INFORMATION
12.1 Toxicity
Toxicity to fish LC50 - Leuciscus idus (Golden orfe) - > 100 mg/l - 96 h
Toxicity to daphnia and EC50 - Daphnia magna (Water flea) - 46,500 mg/l - 48 h
other aquatic
invertebrates
12.2 Persistence and degradability
Biodegradability
13.DISPOSAL CONSIDERATION
13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging
Dispose of as unused product.
14.TRANSPORT INFORMATION
14.1 UN number
ADR/RID: IMDG: IATA:
14.2 UN proper shipping name
ADR/RID : Not dangerous goods
IMDG : Not dangerous goods
IATA : Not dangerous goods
14.3 Transport hazard class(es)
ADR/RID: IMDG: IATA:
14.4 Packaging group
ADR/RID: IMDG: IATA:
14.5 Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
15.REGULATORY INFORMATION
Labelling according Regulation (EC) No 1272/2008 [CLP]
Pictogram
Signal word Warning
Hazard statement(s)
H335 May cause respiratory irritation.
Precautionary statement(s)
P261 Avoid breathing vapours.
According to European Directive 67/548/EEC as amended.
Supplemental Hazard none
Statements
16.OTHER INFORMATION
DDC KİMYA LTD. Provides the information contained herein good faith but makes no representation as to its
comprehensiveness or accuracy. This document is intended only as a guide to the appropriate
precautionary handling of the material by a properly trained person using this product. Individuals
receiving the information must exercise their independent judgement in determining its appropriateness
for a particular purpose.DDC KİMYA LTD. MAKES NO REPRESANTATIONS OR WARRANTIES, EITHER
EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTIBILITY,
FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR
THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, KIMETSAN LTD., WILL NOT BE
RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF RELIANCE UPON THIS INFORMATION